Characterization of Petroleum Crude Oils using Laser Induced Fluorescence

Introduction:

Petroleum is considered as a complex mixture of hydrocarbons compounds that are essentially composed of carbon and hydrogen in a wide variety of molecular arrangements. These hydrocarbons are divided into three main classes – alkanes, cycloalkanes and aromatics. Their average range in crude oil is C5H12 to C18H38 along with heteroatom-containing, oxygen, nitrogenand sulfur. In addition to the previous contents, petroleum oil contains trace amounts of metals such as iron, nickel, copper and vanadium. The physical properties, particularly specific gravity, of the crude oil play a big role in the global petroleum trading. It is defined as the ratio of the mass of a given volume of the oil at 15°C to the mass of an equal volume of pure water at the same temperature. 

laser induced fluorescence
It varies from 0.8 (45.3 API) for the lighter crude oils to over 1.0 (less than 10 API) for heavy crude oil and bitumen . API gravity which is an arbitrary figure and more popular term, can be defined as the inverse measure of the relative density of a petroleum liquid and the densityof water with the formula (API=(141.5/Specific Gravity at 60°F)-131.5). It is clearly seen from the previous relation that the API gravity of the oil increases with the decrease of the specific gravity and vice versa. The API gravity term reflects directly the economic value of the oil and it is also an important factor in shipping and volume calculations.

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